The metric and topological characteristics of the cells (E-cells) at the pe
riphery of a sample of a cellular system are analysed. For two-dimensional
(2D) systems, equations are derived for the number of E-cells per unit leng
th of the boundary and for the distribution f(e) of the number e of cells a
djacent to an E-cell. We obtain simple equations for the average [e], which
depends on the second moment mu(2)(0) of the distribution of number of sid
es of the inner cells and on the curvature of the boundary. For a straight
boundary we derive the approximate relation [e](0) = 4 + mu(2)(0)/12. The r
esults for 2D structures are confronted with direct measurement of the rele
vant quantities in actual networks. The agreement is quite good. We also di
scuss briefly E-cells in three-dimensional structures and obtain equations
for the average number of neighbours of E-cells.