Cation of N-allylbenzothiazolium as a pi-ligand in copper(I) halide complexes: Synthesis and crystal structure of [C7H5NS(C3H5)](+) center dot CuCl2-center dot H2O and [C7H5NS(C3H5)](+) center dot CuCl1.06Br0.94- center dotH2O compounds

Authors
Goreshnik, EA Mys'kiv, MG
Citation
Ea. Goreshnik et Mg. Mys'Kiv, Cation of N-allylbenzothiazolium as a pi-ligand in copper(I) halide complexes: Synthesis and crystal structure of [C7H5NS(C3H5)](+) center dot CuCl2-center dot H2O and [C7H5NS(C3H5)](+) center dot CuCl1.06Br0.94- center dotH2O compounds, POL J CHEM, 73(8), 1999, pp. 1245-1252
Citations number
9
Categorie Soggetti
Chemistry
Journal title
POLISH JOURNAL OF CHEMISTRY
ISSN journal
01375083 → ACNP
Volume
73
Issue
8
Year of publication
1999
Pages
1245 - 1252
Database
ISI
SICI code
0137-5083(199908)73:8<1245:CONAAP>2.0.ZU;2-H
Abstract
By alternating-current electrochemical synthesis crystals of [C7H5NS(C3H5)] (+). CuCl2-. H2O (I) and [C7H5NS(C3H5)](+). CuCl1.06Br0.94-. H2O (II) pi-co mplexes have been obtained and structurally characterized. Owing to the cat ionic form, the ligand is coordinated to Cu atom only through the C=C bond. Due to the bridged role of X(2) atom [X = Cl (I) or statistic mixture Cl, Br (II)], cyclic fragments Cu2X42- appear. Intermolecular hydrogen bonds wi th participation of the water molecule form three-dimensional structure. Th e trigonal-pyramidal copper(I) environment involves three halide atoms tone of them occupies the apical position) and C=C group.