Synthesis and crystal structure of copper(I) chloride pi-complex with 1-allylbenzotriazole of CuCl center dot C6H4N3(C3H5) composition

Authors
Goreshnik, EA
Citation
Ea. Goreshnik, Synthesis and crystal structure of copper(I) chloride pi-complex with 1-allylbenzotriazole of CuCl center dot C6H4N3(C3H5) composition, POL J CHEM, 73(8), 1999, pp. 1253-1258
Citations number
13
Categorie Soggetti
Chemistry
Journal title
POLISH JOURNAL OF CHEMISTRY
ISSN journal
01375083 → ACNP
Volume
73
Issue
8
Year of publication
1999
Pages
1253 - 1258
Database
ISI
SICI code
0137-5083(199908)73:8<1253:SACSOC>2.0.ZU;2-O
Abstract
By alternating-current electrochemical synthesis crystals of CuCl . C6H4N3( C3H5) pi-complex (I) have been obtained and structurally investigated. Due to the coordination of Cu(I) atoms through the nitrogen atom and olefinic g roup of the same molecule, organometallic chains appear. Bridged Cl atoms c ombine these chains into a three-dimensional framework. The trigonal-pyrami dal copper environment involves two CI atoms tone of them occupies the apic al position), nitrogen atom and C=C group.