Synthesis and characterization of the mer-[RuCl3(NO)(dppb)] isomer. X-ray structures of fac-[RuCl3(NO)(dppm)], cis-[RuCl2(dppm)(2)] and mer-[RuCl3(NO)(dppb)] [dppm=1,2-bis(diphenylphosphino)methane and dppb=1,4-bis(diphenylphosphino)butane]

Authors
Batista, AA Pereira, C Wohnrath, K Queiroz, SL Santos, RHD Gambardella, MTD
Citation
Aa. Batista et al., Synthesis and characterization of the mer-[RuCl3(NO)(dppb)] isomer. X-ray structures of fac-[RuCl3(NO)(dppm)], cis-[RuCl2(dppm)(2)] and mer-[RuCl3(NO)(dppb)] [dppm=1,2-bis(diphenylphosphino)methane and dppb=1,4-bis(diphenylphosphino)butane], POLYHEDRON, 18(15), 1999, pp. 2079-2083
Citations number
16
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
POLYHEDRON
ISSN journal
02775387 → ACNP
Volume
18
Issue
15
Year of publication
1999
Pages
2079 - 2083
Database
ISI
SICI code
0277-5387(1999)18:15<2079:SACOTM>2.0.ZU;2-N
Abstract
The fac-[RuCl3(NO)(dppm)] (1) and cis-[RuCl2(dppm)(2)] (2) complexes were o btained with co-crystallization in the solid state from the reaction of RuC l3(NO) with the diphosphine in dichloromethane. mer-[RuCl3(NO)(dppb)] (3) w as obtained from [RuCl3(dppb)(H2O)] by bubbling NO for 30 min in the same s olvent. The crystal and molecular structures of these three compounds have been determined from X-ray studies. (C) 1999 Elsevier Science Ltd. All righ ts reserved.