Human oxyhemoglobin concentrated solution exposed to electrons with average
energy of 10 MeV in doses of 1.7, 2.5 and 5.0 kGy was studied by Mossbauer
spectroscopy and positron life-time technique. Precise measurements of Mos
sbauer spectra of irradiated oxyhemoglobin samples revealed deoxygenation p
rocess and formation of two ferric compounds at 1.7 kGy and ferrous and fer
ric compounds at 2.5 and 5.0 kGy. Positron life-time parameters showed decr
ease of the free volume radius and the total free volume in irradiated oxyh
emoglobin solutions. (C) 1999 Elsevier Science Ltd. All rights reserved.