The radiation-chemical behaviour of isolated organic molecules in solid rar
e gas matrices was studied using a combination of ESR and IR spectroscopy.
The total radiation-chemical yields of degradation of organic molecules in
solid argon and xenon were estimated. The effect of electron scavengers on
the radiolysis of organic molecules in solid rare gases reveals that the ma
in primary process is positive hole transfer from matrix to guest molecule.
ESR spectra of a number of radical cations (alkanes, ethers, arenes) were
characterized in a low-disturbing environment. It was found that the electr
onic characteristics (IP, polarizability) of the matrix used had crucial ef
fect on trapping and reactions of the isolated radical cations. (C) 1999 El
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