Direct displacement of chlorine atoms by alkoxides on chlorinated anthraquinones

Citation
Gv. Malinovskaya et Vp. Anufriev, Direct displacement of chlorine atoms by alkoxides on chlorinated anthraquinones, SYN COMMUN, 29(18), 1999, pp. 3117-3124
Citations number
13
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNTHETIC COMMUNICATIONS
ISSN journal
00397911 → ACNP
Volume
29
Issue
18
Year of publication
1999
Pages
3117 - 3124
Database
ISI
SICI code
0039-7911(1999)29:18<3117:DDOCAB>2.0.ZU;2-G
Abstract
The reaction of 1-chloro-, 2-chloro-, 1,5-dichloro-, 1,8-dichloro-, 1-hydro xy-4-chloro-, 1-hydroxy-2,4-dichloro- and 1,4-dihydroxy-5-chloro-9, 10-anth raquinones with 2-ethoxyethanol activated by fluoride anion in the presence of alumina affords reasonable to high yields of the corresponding mono- an d dialkoxy derivatives.