A new biphenyl-20-crown-6-derived zinc(II) porphyrin dimer with a potentially heterotropic allostery

Authors
Kubo, Y Murai, Y Yamanaka, J Tokita, S Ishimaru, Y
Citation
Y. Kubo et al., A new biphenyl-20-crown-6-derived zinc(II) porphyrin dimer with a potentially heterotropic allostery, TETRAHEDR L, 40(33), 1999, pp. 6019-6023
Citations number
38
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
40
Issue
33
Year of publication
1999
Pages
6019 - 6023
Database
ISI
SICI code
0040-4039(19990813)40:33<6019:ANBZPD>2.0.ZU;2-P
Abstract
Synthesis of a new bis-porphyrinic system coupled with biphenyl-20-crown-6 as an allosteric spacer, 1, is described; the incorporated rotatable biphen yl unit is capable of regulating the porphyrin center-to-center distance by an encapsulated metal ion in the crown-strapped cavity, so that the system displayed a potentially heterotropic allostery at the binding stage with a certain stereogenic alpha, omega-diamine guest, 2. (C) 1999 Elsevier Scien ce Ltd. All rights reserved.