A linear trinuclear Cd-II-Cd-II-Cd-II complex with a mu-acetato bridge: bis{(mu-acetato)[mu-bis(salicylidene)-1,3-propanediaminato]-cadmium(II)}cadmium(II)

Authors
Atakol, O Aksu, M Ercan, F Arici, C Tahir, MN Ulku, D
Citation
O. Atakol et al., A linear trinuclear Cd-II-Cd-II-Cd-II complex with a mu-acetato bridge: bis{(mu-acetato)[mu-bis(salicylidene)-1,3-propanediaminato]-cadmium(II)}cadmium(II), ACT CRYST C, 55, 1999, pp. 1072-1075
Citations number
19
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
55
Year of publication
1999
Part
7
Pages
1072 - 1075
Database
ISI
SICI code
0108-2701(19990715)55:<1072:ALTCCW>2.0.ZU;2-#
Abstract
The title complex, bis(mu-acetato)-1:2 kappa(2)O:O';2:3 kappa(2)O:O'-bis{mu -2,2'-[1,3-propanediylbis(nitrilomethylidene)]di phenolato}-1 kappa(4)N,N', O,O':2 kappa(2)O,O';3 kappa(4)N,N',O,O':2 kappa(2)O,O'-tricadmium(II), [Cd{ Cd(C17H16N2O2)(CH3CO2)}(2)], consists of a doubly oxygen-bridged linear hom otrinuclear complex. The outer Cd-II ions, related by an inversion centre, have an irregular square-pyramidal coordination. The central Cd-II ion has an irregular octahedral coordination and lies on an inversion centre. The m etal-metal bridging distance is 3.2582 (3) Angstrom.