(Z)-N-benzyl-2,3-dihydro-2-(2-methoxybenzylidene)-4H-1,4-benzoxazine

Citation
S. Maiti et al., (Z)-N-benzyl-2,3-dihydro-2-(2-methoxybenzylidene)-4H-1,4-benzoxazine, ACT CRYST C, 55, 1999, pp. 1154-1156
Citations number
17
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
55
Year of publication
1999
Part
7
Pages
1154 - 1156
Database
ISI
SICI code
0108-2701(19990715)55:<1154:(>2.0.ZU;2-1
Abstract
In the title compound, C23H21NO2, the molecule contains three essentially p lanar benzo rings (A, B and C) and displays the Z-configuration. The six-me mbered oxazine ring adopts a half-boat conformation and is fused to phenyl ring A. The dihedral angle between the planar part of the oxazine moiety an d ring A is 4.70(6)degrees. A strong conjugation effect is reflected in the C-O [1.377(3)-1.385(3) Angstrom] and C-N [1.396(2) Angstrom] bond lengths.