Low-temperature phase of bis(2-methoxycarbonyl-2-methylpropyl) 2,5-diisopropylidene-3,4-bis(2-methoxycarbonyl-2-methylpropoxycarbonyl)hex-3-enedioate, a crystal structure with six independent pseudo-related molecules

Authors
Bats, JW Nass, AR Hashmi, ASK
Citation
Jw. Bats et al., Low-temperature phase of bis(2-methoxycarbonyl-2-methylpropyl) 2,5-diisopropylidene-3,4-bis(2-methoxycarbonyl-2-methylpropoxycarbonyl)hex-3-enedioate, a crystal structure with six independent pseudo-related molecules, ACT CRYST C, 55, 1999, pp. 1183-1186
Citations number
10
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
55
Year of publication
1999
Part
7
Pages
1183 - 1186
Database
ISI
SICI code
0108-2701(19990715)55:<1183:LPOB2>2.0.ZU;2-6
Abstract
The crystal structure of the title compound, C38H56O16, is disordered above 298 K. A tripling of the unit cell is observed on cooling. The structure a t 136 K contains six ordered molecules related by pseudo-translation vector s of (1/3,0,-1/3), pseudo-inversion centers and pseudo-twofold screw axes.