KINETICS AND MECHANISM OF OXIDATION OF ALIPHATIC ACETALS WITH N-CHLOROBENZAMIDE

Authors
AHAMED KAB
Citation
Kab. Ahamed, KINETICS AND MECHANISM OF OXIDATION OF ALIPHATIC ACETALS WITH N-CHLOROBENZAMIDE, Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical, 36(3), 1997, pp. 222-224
Citations number
10
Categorie Soggetti
Chemistry
Journal title
Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical → ACNP
ISSN journal
03764710
Volume
36
Issue
3
Year of publication
1997
Pages
222 - 224
Database
ISI
SICI code
0376-4710(1997)36:3<222:KAMOOO>2.0.ZU;2-G
Abstract
The oxidation kinetics of thirteen aliphatic acetals of normal aliphat ic aldehydes and substituted aliphatic aldehydes with aliphatic and su bstituted aliphatic as well as with aromatic alcohols by N-chlorobenza mide (NCB) in aqueous acetic acid medium follows first order and zero order dependence in [NCB] and [acetal] respectively and yields the cor responding esters as the main product of oxidation. (H2OCl)(+) has bee n postulated as the oxidizing species.