We have obtained optical spectra of seven stars in the old galactic cluster
M 67 that are unusual sources of X-rays, and investigate whether the X-ray
emission is due to magnetic activity or to mass transfer. The two binaries
below the giant branch S 1063 and S 1113, the giant with the white dwarf c
ompanion S 1040 and the eccentric binary on the subgiant branch S 1242 show
magnetic activity in the form of Ca II H&K emission and Ha emission, sugge
sting that their X-rays are coronal. The reason for the enhanced activity l
evel in S 1040 is not clear. The two wide, eccentric binaries S 1072 and S
1237 and the blue straggler S 1082 do not show evidence for Ca II H&K emiss
ion. A second spectral component is found in the spectrum of S 1082, most c
learly in the variable Ha absorption profile. We interpret this as a signat
ure of the proposed hot subluminous companion.