Synthesis and crystal structure of hydrogen selenates K(HSeO4)(H2SeO4) andCs(HSeO4)(H2SeO4)

Authors
Troyanov, SI Morozov, IV Zakharov, MA Kemnitz, E
Citation
Si. Troyanov et al., Synthesis and crystal structure of hydrogen selenates K(HSeO4)(H2SeO4) andCs(HSeO4)(H2SeO4), CRYSTALLO R, 44(4), 1999, pp. 560-564
Citations number
15
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
CRYSTALLOGRAPHY REPORTS
ISSN journal
10637745 → ACNP
Volume
44
Issue
4
Year of publication
1999
Pages
560 - 564
Database
ISI
SICI code
1063-7745(199907/08)44:4<560:SACSOH>2.0.ZU;2-G
Abstract
Hydrogen selenates of the compositions K(HSeO4)(H2SeO4) and Cs(HSeO4)(H2SeO 4) are:synthesized by the reaction of alkali metal carbonates with an exces s of the concentrated selenic acid, The X-ray diffraction study showed that both compounds are isostructural to the corresponding hydrogen sulfates, T he difference in the systems of hydrogen bonding are caused by various comb inations of the acceptor functions of the oxygen atoms in the HSeO4 and H2S eO4 groups.