New absorption centres having zero phonon lines at 2678 (332 meV), 2913.6 (
361 meV), 4392.9 (544 meV) and 4442.2 cm(-1) (550 meV) have been produced i
n heavily electron-irradiated and annealed type Ia diamonds. Their temperat
ure dependence and annealing behaviour have been investigated along with th
e effect of the radiation dose and isotopic shifts caused by the substituti
on of N-15 and C-13 for N-14 and C-12, respectively. The results are consis
tent with the centres being caused by electronic transitions. (C) 1999 Publ
ished by Elsevier Science S.A. All rights reserved.