Solvothermal synthesis of the graphitic form of C3N4 as macroscopic sample

The ab initio calculations of the stability of unknown materials present ne w developments in solid state chemistry and can improve the research of new superhard materials. The compound C3N4 is an interesting illustration of s uch a new route for predicting original materials. During approximately the past 10 years five different structures have been predicted: one is two-di mensional (the graphitic form of C3N4) and four are three-dimensional (alph a, beta, a zinc-blende-type with carbon vacancies, a cubic-type isostructur al of the high-pressure variety of Zn2SiO4). Different routes have been inv estigated for preparing one of the previous C3N4 forms (involving PVD, chem ical vapour deposition and high pressures processes). Unfortunately, due to the strong stability of the N-2 molecule, carbon nitrides - deficient in n itrogen - have been obtained in most of the cases. In several attempts, sma ll microcrystallites attributed to a crystallized C3N4 form embedded in an amorphous phase have been isolated. Recently using a solvothermal process: the pyrolysis of melamine in presence of a nitriding solvent (NH,NH,) in hi gh pressure conditions (P=3 GPa, 800 less than or equal to T less than or e qual to 850 degrees C), the graphitic form of C3N4 has been prepared and ch aracterized (X-ray diffraction, scanning electron microscopy, electron prob e micro-analysis, ESCA, infrared spectroscopy). (C) 1999 Elsevier Science S .A. All rights reserved.