Curvature walls and focal conic domains in a lyotropic lamellar phase

Citation
C. Blanc et M. Kleman, Curvature walls and focal conic domains in a lyotropic lamellar phase, EUR PHY J B, 10(1), 1999, pp. 53-60
Citations number
39
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
EUROPEAN PHYSICAL JOURNAL B
ISSN journal
14346028 → ACNP
Volume
10
Issue
1
Year of publication
1999
Pages
53 - 60
Database
ISI
SICI code
1434-6028(199907)10:1<53:CWAFCD>2.0.ZU;2-G
Abstract
In the quasi-ternary CPCl/brine/hexanol lyotropic system, the interface of the L-alpha lamellar and L-3 sponge phases displays a phenomenon of epitaxy : the layers of the lamellar phase tend to make a constant non-trivial angl e with the interface. Thin samples of lamellar phase embedded in the sponge phase are thus submitted to oblique anchoring conditions and defects are c reated in the lamellar phase in order to satisfy the bulk lamellar ordering and the boundary conditions. We have studied small droplets of lamellar ph ase in the sponge phase. They do not exhibit the classic L-alpha defects (f ocal conic domains) but wall defects, which appear in order to satisfy the smectic elasticity and the boundary conditions. Moreover we show through ex periments in controlled geometry that, even in the presence of focal conic domains, wall defects control the size and periodicity of the textures whic h are observed at the interface.