We have fabricated planar c-axis Pb/NCCO junctions and in-plane NCCO bicrys
tal grain boundary junctions. The Pb/NCCO junctions exhibit single-step ela
stic tunneling and sustain hysteretic Josephson supercurrents, evidence tha
t NCCO has an s-wave component to its superconducting order parameter. Tunn
eling spectroscopy on high-resistance Pb/NCCO junctions reveals a semi-gap
of 3-4 meV in the density of states of NCCO and evidence for phonon couplin
g to NCCO quasiparticles. The grain boundary junctions were made by laser a
blating thin NCCO films onto yttrium-stabilized-zirconia bicrystal substrat
es and sustain supercurrents that modulate in applied magnetic field and sh
ow resistively-shunted-junction I-V characteristics.