M. Lorenz et al., Ag-doped double-sided PLD-YBCO thin films for passive microwave devices infuture communication systems, IEEE APPL S, 9(2), 1999, pp. 1936-1939
Pulsed laser deposited (PLD) Ag-doped YBa2Ca3O7-x (YBCO) thin films on both
sides of 3-inch diameter sapphire wafers are used routinely for developmen
t of microwave filters for future communication systems. The reproducibly d
eposited YBCO:Ag films of about 250 nm thickness show critical current dens
ities of 4 MA/cm(2) at 77 K and laterally homogeneous maps of microwave sur
face resistance R of about 45 m Omega at 145 GHz and 77 K measured by an op
en resonator technique. The R at 8.4 GHz and 77 It determined in the center
position of the YBCO:Bg films with a sapphire resonator technique remains
constant at about 380 mu Omega up to a microwave surface magnetic field of
7-10 mT.
Correlations of transport and microwave properties to the film microstructu
re are shown in terms of in-plane epitaxy, size of particulates on the film
s, and composition ratios Cu/O and Y/O, and growth defects like stacking fa
ults as shown by Raman spectroscopy, SEM, and SNMS depth profiling, and TEM
cross sections, respectively. The optimum Ag-content of the PLD-YBCO targe
t was determined to be about 4 weight -%. The results demonstrate that Ag-d
oping supports the PLD process for YBCO in terms of reliability and cost ef
fectiveness.