J. Musolf et Ej. Smith, Sensor-based MOCVD for the growth of low surface resistance YBCO on MgO enabling Q's in excess of 100,000, IEEE APPL S, 9(2), 1999, pp. 2167-2170
Today MOCVD, due to its inherent advantages such as scaleability and throug
hput, is the growth technique of choice for many compound semiconductors as
a production method. However, the use of MOCVD to deposit high quality HTS
material has been impeded by the lack of stable precursors. To overcome th
e problems of limited process reproducibility caused by these shortcomings,
real time control of the gas phase composition by ultraviolet absorption s
ensors has been utilized. This technique allows for a very tight control of
the composition of the deposited material. A surface resistance R-s lower
than 250 mu Omega (77 K, scaled to 10 GHz) could be measured on 700 nm thic
k MOCVD YBCO films. This value correlates very well with the surface resist
ance extracted from measurements of the quality factor Q(0) of a simple mic
rostrip resonator used as a process control monitor. Consistent surface res
istance values below 350 mu Omega prove the reproducibility of the sensor b
ased MOCVD approach. For cellular telecommunica-tion devices at 845 MHz qua
lity factors Q(0) in excess of 100,000 at 77 K are indicative of the excell
ent material quality.