Synthesis and characterization of novel alkylperoxo mononuclear iron(III) complexes with a tripodal pyridylamine ligand: A model for peroxo intermediates in reactions catalyzed by non-heme iron enzymes

Authors
Wada, A Ogo, S Watanabe, Y Mukai, M Kitagawa, T Jitsukawa, K Masuda, H Einaga, H
Citation
A. Wada et al., Synthesis and characterization of novel alkylperoxo mononuclear iron(III) complexes with a tripodal pyridylamine ligand: A model for peroxo intermediates in reactions catalyzed by non-heme iron enzymes, INORG CHEM, 38(16), 1999, pp. 3592
Citations number
20
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
38
Issue
16
Year of publication
1999
Database
ISI
SICI code
0020-1669(19990809)38:16<3592:SACONA>2.0.ZU;2-6
Abstract
Thermodynamically extremely stable alkylperoxo-iron(III) complexes have bee n prepared for the first time from reaction of the ternary iron(III) comple x with a tripodal pyridylamine ligand with alkylperoxide in MeCN. These com plexes have been characterized on the basis of the electronic absorption, E SR, resonance Raman, and ESI mass spectra and cyclic voltammetry.