[(eta(6)-p-Pr(i)C6H4Me)(2)Ru2Mo2O6(OMe)(4)]: a new tetranuclear mixed-metal oxo cluster presenting a cube-based chair structure

Authors
Plasseraud, L Stoeckli-Evans, H Suss-Fink, G
Citation
L. Plasseraud et al., [(eta(6)-p-Pr(i)C6H4Me)(2)Ru2Mo2O6(OMe)(4)]: a new tetranuclear mixed-metal oxo cluster presenting a cube-based chair structure, INORG CH C, 2(8), 1999, pp. 344-346
Citations number
23
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
2
Issue
8
Year of publication
1999
Pages
344 - 346
Database
ISI
SICI code
1387-7003(199908)2:8<344:[ANTM>2.0.ZU;2-C
Abstract
The title complex was obtained by reaction of [(eta(6)-p-Pr'C6H4Me)(4)Ru4Mo 4O16] with methanol in the presence of p-hydroquinone. It contains an Mo2Ru 2O2(OMe)(4) core consisting of two Mo2RuO(OMe)(3) half-cubes fused together to form a choir-like structure. (C) 1999 Elsevier Science S.A. All rights reserved.