Two novel zinc(II) complexes of the 1,8-cross-bridged cyclam ligand and their structures

Authors
Niu, WJ Wong, EH Weisman, GR Lam, KC Rheingold, AL
Citation
Wj. Niu et al., Two novel zinc(II) complexes of the 1,8-cross-bridged cyclam ligand and their structures, INORG CH C, 2(8), 1999, pp. 361-363
Citations number
27
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
2
Issue
8
Year of publication
1999
Pages
361 - 363
Database
ISI
SICI code
1387-7003(199908)2:8<361:TNZCOT>2.0.ZU;2-G
Abstract
Without special precautions to exclude moisture or protic solvents, cross-b ridged cyclam ligand 1 was found to readily complex zinc dichloride and yie ld two types of cis-folded complexes in the solid-state; one a chloride-bri dged dimer and the: other an aqua complex featuring a coordinated [ZnCl4](2 -) counterion. (C) 1999 Elsevier Science S.A. All rights reserved.