On the number of independent reflections in a powder diffraction pattern

Authors
Citation
Wif. David, On the number of independent reflections in a powder diffraction pattern, J APPL CRYS, 32, 1999, pp. 654-663
Citations number
8
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF APPLIED CRYSTALLOGRAPHY
ISSN journal
00218898 → ACNP
Volume
32
Year of publication
1999
Part
4
Pages
654 - 663
Database
ISI
SICI code
0021-8898(19990801)32:<654:OTNOIR>2.0.ZU;2-4
Abstract
Peak overlap in powder diffraction patterns necessarily implies that the nu mber of visible peaks is less than the number of Bragg peaks. While the num ber of Bragg reflections is easily enumerated, the number of statistically independent Bragg peaks is not. In this paper, it is shown that, although t here is no single or simple answer to this problem, Bragg peak intensity co rrelation is a well behaved statistical quantity that can be used to expres s a measure of the number of independent peaks.