Synthesis and molecular structure of [CpRu(1,4,7-S3C6H12)]O3SCF3

Authors
Green, M Draganjac, M Jiang, YJ Cordes, AW
Citation
M. Green et al., Synthesis and molecular structure of [CpRu(1,4,7-S3C6H12)]O3SCF3, J CHEM CRYS, 29(3), 1999, pp. 273-276
Citations number
30
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY
ISSN journal
10741542 → ACNP
Volume
29
Issue
3
Year of publication
1999
Pages
273 - 276
Database
ISI
SICI code
1074-1542(199903)29:3<273:SAMSO[>2.0.ZU;2-E
Abstract
The isolation and characterization of [CpRu(9S3)](O3SCF3), where 9S3 = 1,4, 7-trithiacyclononane, is reported. The title compound crystallizes in the o rthorhombic space group Pbca: a = 10.2542(18), b = 14.8991(13), c = 22.4832 (18) Angstrom, and Z = 8. The Ru atom is sandwiched between the rr-bound cy clopentadienyl ligand and the 983 ligand, bonding to all three of the sulfu r atoms in the 9S3. The Ru-S distances are 2.2991(10), 2.2979(11), and 2.30 55(10) a. The C-S distances range from 1.819(4) to 1.852(5) Angstrom in the trithiacyclononane ring.