SYNTHESIS, CHARACTERIZATION AND AQUATION KINETICS OF A NEW TRANS DIASTEREOISOMER OF THYL-1,4,8,11-TETRAAZACYCLOTETRADECANE)COBALT(III) PERCHLORATE

Authors
CHEN BH LAI CY YUAN YH CHUNG CS
Citation
Bh. Chen et al., SYNTHESIS, CHARACTERIZATION AND AQUATION KINETICS OF A NEW TRANS DIASTEREOISOMER OF THYL-1,4,8,11-TETRAAZACYCLOTETRADECANE)COBALT(III) PERCHLORATE, Journal of the Chemical Society. Dalton transactions, (20), 1994, pp. 2959-2961
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
20
Year of publication
1994
Pages
2959 - 2961
Database
ISI
SICI code
0300-9246(1994):20<2959:SCAAKO>2.0.ZU;2-H
Abstract
A new trans diastereoisomer of thyl-1,4,8,11-tetraazacyclotetradecane) cobalt(III) perchlorate has been prepared, and the electronic absorpti on and infrared spectral data studied. The assignments of the structur e of the isomer have been accomplished by thorough stereochemical anal ysis combined with H-1 and C-13 NMR spectral data. Aquation kinetics h ave been studied at various temperatures and activation parameters det ermined. The results indicate a dissociative activation with retention of configuration and a distorted-square pyramidal activated complex.