ON THE HYDROLYSIS OF NIOBIUM(V) AND TANTALUM(V) IN 3-MOL DM(-3) KCL AT 25-DEGREES-C .1. CONSTRUCTION OF A THERMODYNAMIC MODEL FOR NB-V

Authors
ETXEBARRIA N FERNANDEZ LA MADARIAGA JM
Citation
N. Etxebarria et al., ON THE HYDROLYSIS OF NIOBIUM(V) AND TANTALUM(V) IN 3-MOL DM(-3) KCL AT 25-DEGREES-C .1. CONSTRUCTION OF A THERMODYNAMIC MODEL FOR NB-V, Journal of the Chemical Society. Dalton transactions, (20), 1994, pp. 3055-3059
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
20
Year of publication
1994
Pages
3055 - 3059
Database
ISI
SICI code
0300-9246(1994):20<3055:OTHONA>2.0.ZU;2-7
Abstract
The hydyolysis of Nb-V in 3.0 mot dm(-3) KCl has been studied by poten tiometric measurement of the H3O+ ion concentration with a glass elect rode. The results have been treated both graphically and numerically, and show that the hydrolysis process can be considered to be homonucle ar. A comparison has been made with other data in the literature and a hydrolysis model for Nb-V proposed using the modified Bromley theory.