Insertion of SO2 into the P-P bond of Fe-2(CO)(6)(mu-(P2Bu2)-Bu-t)

Authors
Kabir, SE Ruf, M Vahrenkamp, H
Citation
Se. Kabir et al., Insertion of SO2 into the P-P bond of Fe-2(CO)(6)(mu-(P2Bu2)-Bu-t), J ORGMET CH, 584(2), 1999, pp. 344-346
Citations number
13
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
584
Issue
2
Year of publication
1999
Pages
344 - 346
Database
ISI
SICI code
0022-328X(19990723)584:2<344:IOSITP>2.0.ZU;2-U
Abstract
The P-P bond in the dinuclear iron complex Fe-2(CO)(6)(mu-(P2Bu2)-Bu-t) was found to be labile towards SO2 insertion, yielding Fe-2(CO)(6)(mu-(BuP)-Bu -t-SO2-(PBu)-Bu-t), which was characterized by a structure determination. ( C) 1999 Elsevier Science S.A. All rights reserved.