Synthesis and reactivity of [((RRN)-R-1-N-2)(2)PH]Fe(CO)(4) complexes. X-ray crystal structure of [Ph2N)(2)PH]Fe(CO)(4) (vol 570, pg 195, 1998)

Authors
Brunet, JJ Chauvin, R Diallo, O Donnadieu, B Jaffart, J Neibecker, D
Citation
Jj. Brunet et al., Synthesis and reactivity of [((RRN)-R-1-N-2)(2)PH]Fe(CO)(4) complexes. X-ray crystal structure of [Ph2N)(2)PH]Fe(CO)(4) (vol 570, pg 195, 1998), J ORGMET CH, 584(2), 1999, pp. 389-395
Citations number
29
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
584
Issue
2
Year of publication
1999
Pages
389 - 395
Database
ISI
SICI code
0022-328X(19990723)584:2<389:SARO[C>2.0.ZU;2-M
Abstract
KHFe(CO)(4) reacts with tris(amino)phosphines by substitution at phosphorus leading to [bis(amino)phosphine]tetracarbonyliron complexes [((RRN)-R-1-N- 2)(2)PH]Fe(CO)(4). The X-ray structure has been determined for R-1 = R-2 = Ph. Deprotonation of these complexes with KH affords stable potassium phosp hidotetracarbonylferrates which can be alkylated or acylated at phosphorus. (C) 1999 Elsevier Science S.A. All rights reserved.