HYDROTALCITE-LIKE COMPOUNDS FOR LIQUID-PHASE OXIDATION OF BENZYLIC HYDROCARBONS

Authors
CHOUDARY BM BHUMA V NARENDER N
Citation
Bm. Choudary et al., HYDROTALCITE-LIKE COMPOUNDS FOR LIQUID-PHASE OXIDATION OF BENZYLIC HYDROCARBONS, Indian journal of chemistry. Sect. B: organic chemistry, including medical chemistry, 36(3), 1997, pp. 278-280
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Indian journal of chemistry. Sect. B: organic chemistry, including medical chemistry → ACNP
ISSN journal
03764699
Volume
36
Issue
3
Year of publication
1997
Pages
278 - 280
Database
ISI
SICI code
0376-4699(1997)36:3<278:HCFLOO>2.0.ZU;2-D
Abstract
Hydrotalcite-like compounds (HTlcs - The homogeneously dispersed dispe rsed mixed metallic oxides) have been devised and used for the liquid- phase oxidation of benzylic hydrocarbons for the first time, as an alt ernative to the heterogeneously dispersed mixed oxides and supported m etal catalysts, as an exploratory work. HTlcs such as calcined ZnCrCO3 , NiAlCO3, CuZnAlCO3 and MgAlCO3 (hydrotalcite) have been used in our studies and ZnCrCO3 system is the best, both in terms of turnover numb er and conversion.