I. Dragieva et al., Boron containing nanoparticles and their contribution to the theory and production of new materials, NANOSTR MAT, 12(5-8), 1999, pp. 613-616
The nanosized CoxByHz particles synthesized by the two ('tea' and 'antigrav
ity') methods based on borohydride reduction process have been subjected to
additional compositional study in this work. For the particles obtained by
'antigravity' method, the estimated Co/B ratio is around 1.5, which may be
due to the substitution of one boron by one hydrogen atom, considering its
position as a nearest neighbor atom into cobalt atom surrounding. The comp
ositional studies of particles in respect to boron and hydrogen content sta
nd by such assumption. We suggest the hypothesis that the presence of two s
tates of B 1s electron (as well as of C 1s, N 1s or O 1s) is responsible to
the appearance of an amorphous structure in all materials produced and app
lied as amorphous materials. We suggest the hypothesis the nanocrystalline
particles obtained by the 'antigravity' method, containing only 'odd' eleme
nts, posses predetermined on a quantum level unusual properties. (C) 1999 A
cta Metallurgica Inc.