Ep. Yelsukov et al., Structure, phase composition and magnetic characteristics of the nanocrystalline iron obtained by mechanical milling in heptane, NANOSTR MAT, 12(1-4), 1999, pp. 483-486
The paper states that in the absence of carbon in the particle bulk the for
mation of the nanocrystalline state in alpha-Fe by mecanical milling is not
accopanied by the change in structural and magnetic parameters, with the e
xception of the increase of the coercivity. In case the source of carbon is
present all the changes in magnetic characteristics of nanocrystalline alp
ha-Fe, caused by milling time increase, may be explained by carbon segregat
ion in boundary zones with the formation of supersaturated solid solutions
and Fe3C. (C) 1999 Acta Metallurgica Inc.