Yd. Jo et al., EFFECT OF ACTIVE-SITE DISTRIBUTION ON LIQUID-PHASE OLEFIN HYDROGENATION OVER POLYMER-SUPPORTED PALLADIUM COMPLEX, The Korean journal of chemical engineering, 14(2), 1997, pp. 125-128
Chloromethylated polystyrene beads with different distributions have b
een prepared and phosphinated. PdCl2 was supported on the phosphinated
supports to give polymer-supported Pd complex catalysts with differen
t active site distributions. The effect of active site distribution on
catalytic activity was investigated in the hydrogenation of olefins.