Synthesis and structure of the niobium complexonate [Nb2S4(Py(COO)(2))(2)(H2O)(2)] center dot 3H(2)O

Authors
Sokolov, MN Geras'ko, OA Virovets, AV Fedorov, VE
Citation
Mn. Sokolov et al., Synthesis and structure of the niobium complexonate [Nb2S4(Py(COO)(2))(2)(H2O)(2)] center dot 3H(2)O, RUSS J C CH, 24(11), 1998, pp. 775-780
Citations number
12
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY
ISSN journal
10703284 → ACNP
Volume
24
Issue
11
Year of publication
1998
Pages
775 - 780
Database
ISI
SICI code
1070-3284(199811)24:11<775:SASOTN>2.0.ZU;2-O
Abstract
The complex [Nb2S4(Py(COO)(2))(2)(H2O)(2)] . 3H(2)O was synthesized and stu died by X-ray diffraction analysis. The crystals are monoclinic, space grou p P2(1)/n, a = 21.075(2), b = 11.203(1), c = 21.749(2) Angstrom, beta = 1 1 0.631(9)degrees, V = 4805.7(8) Angstrom(3), Z = 8. The structure contains t wo crystallographically independent types of molecules having identical str ucture and close geometric parameters. The complex synthesized is the first structurally characterized niobium complexonate.