Mild template synthesis of (2,8-dithio-3,7-diaza-5-oxanonanedithioamido-1,9)aquohydroxocobalt(III) in the KCoFe(CN)(6) gelatin-immobilized matrix systems

Authors
Mikhailov, OV Khamitova, AI
Citation
Ov. Mikhailov et Ai. Khamitova, Mild template synthesis of (2,8-dithio-3,7-diaza-5-oxanonanedithioamido-1,9)aquohydroxocobalt(III) in the KCoFe(CN)(6) gelatin-immobilized matrix systems, RUSS J C CH, 24(11), 1998, pp. 807-810
Citations number
16
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY
ISSN journal
10703284 → ACNP
Volume
24
Issue
11
Year of publication
1998
Pages
807 - 810
Database
ISI
SICI code
1070-3284(199811)24:11<807:MTSO(>2.0.ZU;2-N
Abstract
The complexation processes occurring in the cobalt(III) hexacyanoferrate(II )-gelatin-immobilized matrix systems contacting aqueous solutions of dithio oxamide [GRAPHICS] and formaldehyde are investigated in an alkaline medium (pH > 10). Under th ese specific conditions, the cited organic compounds function as ligsons in the template synthesis, eventually yielding the CoL(OH)(H2O) (L = 2,8-dith io-3,7-diaza-5-oxanonanedithioamide-1,9) chelate. A plausible scheme is sug gested for the synthesis.