Sequential anionic 1,3 ester shifts and intramolecular Stille couplings: Anew protocol for the concise assembly of functionalized polycyclic dienes

Authors
Piers, E Romero, MA Walker, SD
Citation
E. Piers et al., Sequential anionic 1,3 ester shifts and intramolecular Stille couplings: Anew protocol for the concise assembly of functionalized polycyclic dienes, SYNLETT, (7), 1999, pp. 1082-1084
Citations number
27
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNLETT
ISSN journal
09365214 → ACNP
Issue
7
Year of publication
1999
Pages
1082 - 1084
Database
ISI
SICI code
0936-5214(199907):7<1082:SA1ESA>2.0.ZU;2-A
Abstract
The novel, functionalized tricycles 24-26 are readily synthesized via conci se routes that employ key tandem anionic 1,3-ester shift and intramolecular Stille coupling protocols. The potential value of this methodology is demo nstrated further by the preparation of the struturally unique tetraquinane keto ester 31.