Macrocyclic studies of EZ and ZZ 12-membered aza macrocycles; Novel molecular rearrangement observed

Citation
E. Bourque et al., Macrocyclic studies of EZ and ZZ 12-membered aza macrocycles; Novel molecular rearrangement observed, SYNLETT, (7), 1999, pp. 1115-1117
Citations number
14
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNLETT
ISSN journal
09365214 → ACNP
Issue
7
Year of publication
1999
Pages
1115 - 1117
Database
ISI
SICI code
0936-5214(199907):7<1115:MSOEAZ>2.0.ZU;2-A
Abstract
EZ and ZZ hetero macrocyclic dienes 13a and 14b are generated respectively by an intramolecular displacement of alpha-chloroketones 11a and 11b using trifluoroacetamide as nucleophilic agent. Novel molecular rearrangements we re observed.