Convenient synthesis of dithiooxamides from N-arylimino-1,2,3-dithiazoles

Authors
Besson, T Rees, CW Thiery, V
Citation
T. Besson et al., Convenient synthesis of dithiooxamides from N-arylimino-1,2,3-dithiazoles, SYNTHESIS-S, (8), 1999, pp. 1345-1348
Citations number
14
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
SYNTHESIS-STUTTGART
ISSN journal
00397881 → ACNP
Issue
8
Year of publication
1999
Pages
1345 - 1348
Database
ISI
SICI code
0039-7881(199908):8<1345:CSODFN>2.0.ZU;2-R
Abstract
Among several useful transformations of the readily available N-arylimino-1 ,2,3-dithiazoles 1 is their rapid conversion by lithium aluminum hydride in to the rearranged N-aryldithiooxamides, ArNHCSCSNH2, thus providing a two s tep synthesis of these unsymmetrical rubeanic acid derivatives from ArNH2 ( 9 examples).