The mild oxidation of nitrile oxides affords a convenient entry to nitrosocarbonyl intermediates, versatile tools in organic syntheses.

Authors
Quadrelli, P Mella, M Invernizzi, AG Caramella, P
Citation
P. Quadrelli et al., The mild oxidation of nitrile oxides affords a convenient entry to nitrosocarbonyl intermediates, versatile tools in organic syntheses., TETRAHEDRON, 55(34), 1999, pp. 10497-10510
Citations number
41
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON
ISSN journal
00404020 → ACNP
Volume
55
Issue
34
Year of publication
1999
Pages
10497 - 10510
Database
ISI
SICI code
0040-4020(19990820)55:34<10497:TMOONO>2.0.ZU;2-Y
Abstract
Nitrile oxides are oxidized by tertiary amine N-oxides in different solvent s at room temperature to afford in the presence of dienes nitrosocarbonyl a dducts in fair yields. The mild conditions used in oxidizing a variety of n itrile oxides promise a wide application of this method in synthetic proces ses. (C) 1999 Elsevier Science Ltd. All rights reserved.