Intramolecular aromatic 1,5-hydrogen transfer in free radical reactions. II. Rearrangement of iodobenzophenones.

Authors
Cummins, JM Dolling, UH Douglas, AW Karady, S Leonard, WR Marcune, BF
Citation
Jm. Cummins et al., Intramolecular aromatic 1,5-hydrogen transfer in free radical reactions. II. Rearrangement of iodobenzophenones., TETRAHEDR L, 40(34), 1999, pp. 6153-6156
Citations number
8
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
40
Issue
34
Year of publication
1999
Pages
6153 - 6156
Database
ISI
SICI code
0040-4039(19990820)40:34<6153:IA1TIF>2.0.ZU;2-9
Abstract
Products derived from the homolysis of the aromatic C-I bond of ortho-iodob enzophenones by photolysis or tributyltin radicals indicate 1,5-hydrogen mi gration. The reactions include iodine migration, hydrogen abstraction and a rylation. (C) 1999 Elsevier Science Ltd. All rights reserved.