EPR spectra of VO2+ doped ammonium oxalate monohydrate single crystals

Citation
B. Karabulut et R. Tapramaz, EPR spectra of VO2+ doped ammonium oxalate monohydrate single crystals, Z NATURFO A, 54(6-7), 1999, pp. 370-374
Citations number
11
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES
ISSN journal
09320784 → ACNP
Volume
54
Issue
6-7
Year of publication
1999
Pages
370 - 374
Database
ISI
SICI code
0932-0784(199906/07)54:6-7<370:ESOVDA>2.0.ZU;2-S
Abstract
The EPR spectra of VO2+ ions in ammonium oxalate monohydrate, [(NH4)(2)C2O4 . H2O], single crystals have been studied at room temperature and at 113 K in mutually three perpendicular planes. The spin Hamiltonian parameters ar e determined using a numerical technique together with a trial and error pr ocedure to resolve the single crystal spectra. The parallel and perpendicul ar components of axially symmetric g and hyperfine tensors for VO2+ ion in ammonium oxalate monohydrate single crystal are determined, and the results are discussed.