Ligand exchange reactions of NiCl2(PPh3)(2) with O(S)-N-S ligands

Citation
S. Sawusch et U. Schilde, Ligand exchange reactions of NiCl2(PPh3)(2) with O(S)-N-S ligands, Z NATURFO B, 54(7), 1999, pp. 881-886
Citations number
13
Categorie Soggetti
Chemistry
Journal title
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES
ISSN journal
09320776 → ACNP
Volume
54
Issue
7
Year of publication
1999
Pages
881 - 886
Database
ISI
SICI code
0932-0776(199907)54:7<881:LERONW>2.0.ZU;2-E
Abstract
Ligand exchange reactions of NiCl2(PPh3)(2) with O(S)boolean AND N boolean AND S ligands were studied. Oxidation products of O boolean AND N boolean A ND S ligands have been characterized and their structures determined: 3-met hyl-4H-benzo [b] [1,4]thiazin-2-yl-phenylmethanone / 2-methyl-benzo[d][1,3] thiazole (mixed crystal); [2-iminoisopropyl-thiophenolato(2-)] (triphenyl-p hosphane)-nickel(II); 1-phenyl-3-methyl-4-(benzoyl-thiobenzoylhydrazono) [1 -phenyl-3-methyl-4-(benzoyl-thiobenzoylhydrazono)-pyrazol-5-thianato](triph enyl-phosphane)-nickel(II).