The usefulness of photoacoustic techniques in characterizing the thermal pr
operties of kaolinite clays, which are a very abundant mineral in some regi
ons of Brazil, was investigated. Different behavioural patterns are observe
d below and above a heating temperature of 950 degrees C and can be attribu
ted to the change from metakaolinite to an amorphous three-dimensional mine
ral which crystallises to mullite and crystobalite above 1200 degrees C. Th
e implications of the results in the manufacture of clay bricks are briefly
considered. This is important in tropical regions where a knowledge of the
thermal properties of materials used in the building construction industry
is highly desirable.