Forces between surfaces in the presence of a cationic polyelectrolyte and an anionic surfactant

An atomic force microscope has been used to investigate the interaction for ces between a mica surface and a colloidal glass sphere in the presence of a high molecular weight cationic polyelectrolyte, and the anionic surfactan t sodium dodecylbenzenesulfonate (SDbS). The effect of addition of SDbS on the interaction forces between the polyelectrolyte coated surfaces was inve stigated. At low concentrations of SDbS the electrostatic repulsion initial ly present was progressively neutralized as a function of increasing surfac tant concentration. Neutralization resulted in a strong attraction between the surfaces. As the SDbS concentration was increased further, additional s urfactant association took place and the surfaces were recharged. At these surfactant concentrations the surfaces became less attractive at small sepa rations. At high SDbS concentrations the interaction profile became purely repulsive as the surfaces were recharged. Diffuse double layer potentials d erived from the direct force measurement data correlated well with zeta-pot ential measurements of silica particles treated with the polyelectrolyte an d surfactant. Particulate stability behaviour was also seen to compare well with the force measurement and electrostatic potential data. (C) 1999 Else vier Science B.V. All rights reserved.