Heterobimetallic iron-platinum phosphino enolate, silyl complexes

Authors
Braunstein, P Stahrfeldt, T Fischer, J
Citation
P. Braunstein et al., Heterobimetallic iron-platinum phosphino enolate, silyl complexes, CR AC S IIC, 2(5-6), 1999, pp. 273-282
Citations number
34
Categorie Soggetti
Chemistry
Journal title
COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE C-CHIMIE
ISSN journal
13871609 → ACNP
Volume
2
Issue
5-6
Year of publication
1999
Pages
273 - 282
Database
ISI
SICI code
1387-1609(199905/06)2:5-6<273:HIPESC>2.0.ZU;2-L
Abstract
In combining the heterobimetallic chemistry of silyl complexes with that of phosphino enolate ligands, we present here the first: heterometallic compl exes containing a chelating phosphino enolate ligand and describe the cryst al structure of [NMe4] [(OC)(3){(MeO)(3)Si}Fe(mu-PPh2)Pt {Ph2PCH ... C(... O)Ph}] (3e). The presence of the enolato function and the negative charge o f complexes 3a-e make them good candidates for reactions with electrophiles and we report preliminary results involving organic isocyanates. (C) Acade mie des sciences/Elsevier, Paris.