The Li-Mn-O materials described here were obtained by drying liquid gels at
low-surface tension conditions, a process which produces high surface area
disordered materials in which the microporous structure can be controlled
with simple manipulations of the parent gel. The technique of synthesis is
simple, inexpensive, and in general may be applied to other intercalation c
ompounds synthesized via sol-gel routes. The aerogels offer a direct way to
study the interconnected solid network assembled by sol-gel processes, whi
ch would collapse if processed by normal dehydration. Since the interconnec
ted solid network is preserved in the aerogel, the properties such as high
specific surface area and high specific energy observed in the aerogel repr
esent inherent properties of the network formed in the liquid gel stage. (C
) 1999 The Electrochemical Society. S1099-0062(99)05-029-4. All rights rese
rved.