Resolution of enantiomer signals by diamagnetic lanthanum(III)-N,N,N ' N '-tetrakis (2-pyridinylmethyl)-(R)-propylenediamine complex in H-1 NMR

Authors
Sato, J Jin, HY Omata, K Kabuto, K Sasaki, Y
Citation
J. Sato et al., Resolution of enantiomer signals by diamagnetic lanthanum(III)-N,N,N ' N '-tetrakis (2-pyridinylmethyl)-(R)-propylenediamine complex in H-1 NMR, ENANTIOMER, 4(2), 1999, pp. 147-150
Citations number
10
Categorie Soggetti
Chemistry
Journal title
ENANTIOMER
ISSN journal
10242430 → ACNP
Volume
4
Issue
2
Year of publication
1999
Pages
147 - 150
Database
ISI
SICI code
1024-2430(1999)4:2<147:ROESBD>2.0.ZU;2-C
Abstract
A La(III) complex, La-(R)-tppn (tppn=N,N,N,N'-tetrakis(2-pyridinylmethyl)-( X)-propylendiamine), is reported for the first time to resolve the enantiom er signals of alpha-amino acids in weakly acidic solution as a diamagnetic lanthanide complex. The induced signal separation showed good correspondenc e between the relative position of the enantiomer signals and the absolute configuration of alpha-amino acids.