Synthesis of dihydrofuro and benzofuro benzopyran-2[H]-one

Authors
Citation
Ss. Soman, Synthesis of dihydrofuro and benzofuro benzopyran-2[H]-one, I J CHEM B, 38(5), 1999, pp. 545-547
Citations number
8
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY
ISSN journal
03764699 → ACNP
Volume
38
Issue
5
Year of publication
1999
Pages
545 - 547
Database
ISI
SICI code
0376-4699(199905)38:5<545:SODABB>2.0.ZU;2-0
Abstract
2,5-Dimethyl-9-hydroxy-4-(propen-2-yl)-dihydrofuro[3,2-g][1]benzopyran-7[H] -one 4 has been prepared from 7,8-dihydroxy4-methyl coumarin 1 by allylatio n, Claisen rearrangement and cyclisation, while benzofnro[3,2-g]-11-hydroxy -4-methylbenzopyran2[H]-one 9 has been prepared from 1 by condensing it wit h 2-bromocyclohexanone followed by cyclisation and dehydrogenation.