Bis(1-benzyl-4-aza-1-azoniabicyclo[2.2.2]octane) peroxodisulfate: A mild and efficient oxidant for oxidation of thiols, sulfides and aromatic amines to the corresponding disulfides, sulfoxides and azo compounds
Ar. Hajipour et al., Bis(1-benzyl-4-aza-1-azoniabicyclo[2.2.2]octane) peroxodisulfate: A mild and efficient oxidant for oxidation of thiols, sulfides and aromatic amines to the corresponding disulfides, sulfoxides and azo compounds, I J CHEM B, 38(5), 1999, pp. 607-610
Citations number
21
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY
Bis(1-benzyl-4-aza-1-azoniabicyclo[2.2.2]octane) peroxodisulfate (BAABCPS)
1, readily prepared as orange solid from commercially available 1,4-diazabi
cyclo[2.2.2]octane (DABCO) and potassium peroxodisulfate converts thiols, s
ulfoxides and aromatic amines to the corresponding disulfides, sulfoxides a
nd azo compounds respectively.