Photon echo and stimulated photon echo study of various collisional-relaxation channels

Collisional relaxation in SF6 gas and its mixtures with He and Xe is studie d by photon echo and stimulated photon echo methods from the standpoint of the possibility of identifying the contributions of different types of coll isions. The nonexponential nature of the kinetic curve of the photon echo i s clearly observed for pure SF6, it is weaker in the mixture SF6+Xe, and it is virtually completely absent for high degrees of dilution of SF6 with he lium. These features can be explained on the basis of estimates, made from experimental data, of the critical delay between the exciting pulses (for w hich the nonexponential behavior should be most strongly manifested). In pu re SF6 it is possible to distinguish the contribution of the inelastic chan nel (rotational relaxation) and the contribution of weak collisions. To dis tinguish successfully the relaxation channels in mixtures with buffer gases a heavier buffer gas and a much better time resolution must be used. It is shown that data obtained on the orientation and alignment relaxation rates by the stimulated photon echo method can serve as an upper limit for the r ates of inelastic processes which cannot be measured by the photon echo met hod. The combined use of photon echo and stimulated photon echo methods mad e it possible to obtain data on the cross sections for elastic and inelasti c scattering of the collisional pairs SF6-SF6, SF6-Xe, and SF6-He. (C) 1999 American Institute of Physics. [S1063-7761(99)00507-7].